Thermochromic Absorption And Photoluminescence In [pt(ppy)(mu-ph(2)pz)](2)

Author(s)

Aaron A. Rachford
Felix N. Castellano, Bowling Green State UniversityFollow

Document Type

Article

Abstract

The temperature effects on the spectral properties and photophysics of a new d(8)-d(8) dinuclear Pt-II chromophore, [Pt(ppy)(mu-Ph(2)pz)](2) (ppy is 2-phenylpyridine and Ph(2)pz is 3,5-diphenylpyrazolate), have been investigated. The thermochromic shifts are tentatively ascribed to intramolecular sigma interactions between the two pseudocofacial d(Z2) orbitals. Substantial emission profile changes occur in the solid state, solution, and doped polymer films.

Copyright Statement

Publisher PDF

Repository Citation

Rachford, Aaron A. and Castellano, Felix N., "Thermochromic Absorption And Photoluminescence In [pt(ppy)(mu-ph(2)pz)](2)" (2009). Chemistry Faculty Publications. 67.
https://scholarworks.bgsu.edu/chem_pub/67

Publication Date

12-2009

Publication Title

Inorganic Chemistry

DOI

https://doi.org/10.1021/ic901156z

Start Page No.

10865

End Page No.

10867