Chemistry Faculty Publications
Document Type
Article
Abstract
The temperature effects on the spectral properties and photophysics of a new d(8)-d(8) dinuclear Pt-II chromophore, [Pt(ppy)(mu-Ph(2)pz)](2) (ppy is 2-phenylpyridine and Ph(2)pz is 3,5-diphenylpyrazolate), have been investigated. The thermochromic shifts are tentatively ascribed to intramolecular sigma interactions between the two pseudocofacial d(Z2) orbitals. Substantial emission profile changes occur in the solid state, solution, and doped polymer films.
Copyright Statement
Publisher PDF
Repository Citation
Rachford, Aaron A. and Castellano, Felix N., "Thermochromic Absorption And Photoluminescence In [pt(ppy)(mu-ph(2)pz)](2)" (2009). Chemistry Faculty Publications. 67.
https://scholarworks.bgsu.edu/chem_pub/67
Publication Date
12-2009
Publication Title
Inorganic Chemistry
DOI
https://doi.org/10.1021/ic901156z
Start Page No.
10865
End Page No.
10867