Chemistry Faculty Publications

Document Type

Article

Abstract

The temperature effects on the spectral properties and photophysics of a new d(8)-d(8) dinuclear Pt-II chromophore, [Pt(ppy)(mu-Ph(2)pz)](2) (ppy is 2-phenylpyridine and Ph(2)pz is 3,5-diphenylpyrazolate), have been investigated. The thermochromic shifts are tentatively ascribed to intramolecular sigma interactions between the two pseudocofacial d(Z2) orbitals. Substantial emission profile changes occur in the solid state, solution, and doped polymer films.

Publication Date

12-2009

Publication Title

Inorganic Chemistry

Volume

48

Issue

23

Start Page No.

10865

End Page No.

10867

DOI

10.1021/ic901156z

Included in

Chemistry Commons

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